| Unlock This | How to Unlock |
| Anna Williams | Beat the game in Story Mode twice |
| Baek | Beat the game in Story Mode 3 times |
| Devil Jin | Complete the Devil Within game or fight in 200 matches. |
| Eddy Gordo | Eddy is an extra outfit you buy for Christie (500,000G on console instead of the 400,000G price tag on the arcade version). |
| Bruce Irvin | Beat Story Mode 4 times |
| School Girl Ling | Get 50 wins in vs mode, then press RP to select the character. |
| Wang Jinrei | Beat Story Battle or Time Attack mode 5 times with a different character. |
| Heihachi | Beat Story Battle or Time Attack mode 9 times with a different character. |
| Mokujin | Beat Story Battle or Time Attack mode 8 times with a different character. |
| Ganryu | Beat Story Battle or Time Attack mode 7 times with a different character. |
| Kuma | Beat Story Battle or Time Attack mode 6 times with a different character. |
| Roger Jr. | Beat Story Battle or Time Attack mode once, with any character. |
